Singly Occupied Molecular Orbital?Highest Occupied Molecular Orbital (SOMO?HOMO) Conversion
نویسندگان
چکیده
Singly occupied molecular orbital?highest orbital (SOMO?HOMO) conversion (inversion), SHC, is a phenomenon in which the SOMO lower energy than doubly orbitals (DOMO, HOMO). A non-Aufbau electronic structure leads to unique properties such as switch bond dissociation and generation of high-spin species on one-electron oxidation. In addition, pronounced photostability these has been reported recently for application organic light-emitting devices. this review article, we summarise chemistry SOMO?HOMO converted (inverted) date.
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ژورنال
عنوان ژورنال: Australian Journal of Chemistry
سال: 2021
ISSN: ['0004-9425', '1445-0038']
DOI: https://doi.org/10.1071/ch21186